Structure and Optical Properties of an Ag135Cu60 Nanocluster Incorporating an Ag135 Buckminsterfullerene-like Topology

Metal nanoclusters are nanoscale materials that bridge the gap between molecules and metals, exhibiting unique physicochemical properties, especially in the study of the relationship between atomic structure and physical properties. In recent years, researchers have shown great interest in organic ligand-protected metal nanoclusters due to their pr...

Impact of Truck Electrification on Air Pollution Disparities in the United States

Academic Background As global climate change intensifies and air pollution becomes increasingly severe, reducing carbon emissions and pollutant emissions in the transportation sector has become a focus for governments and research institutions worldwide. Heavy-duty trucks (Class 8), as the primary means of freight transport in the United States, co...

Economic Costs of Wind Erosion in the United States

Wind erosion and the resulting dust issues have profound impacts on the environment and human society. Since the 1990s, despite significant changes in climate and socioeconomic conditions, the United States has not conducted a comprehensive assessment of the economic costs of wind erosion. In recent years, with global warming, increasing droughts, ...

Towards Sustainable Perovskite Light-Emitting Diodes

As global attention to energy efficiency and environmental sustainability continues to grow, light-emitting diode (LED) technology has become a mainstream choice in the lighting and display sectors. However, despite significant advancements in the energy efficiency and performance of traditional LEDs, their reliance on rare materials during manufac...

Covalent Heterostructures of Ultrathin Amorphous Carbon Nitride and Si for High-Performance Vertical Photodiodes

Carbon nitride (CN), as a two-dimensional n-type semiconductor material, exhibits great potential in light-driven energy conversion and environmental applications due to its excellent photocatalytic activity and stability. However, despite its outstanding performance in photocatalysis, the application of CN in optoelectronic devices, especially sil...

Nickel-Mediated Aerobic C(sp2)–Nucleophile Coupling Reactions for Late-Stage Diversification of Aryl Electrophiles

In the field of medicinal chemistry, molecular diversification is a crucial step in the discovery of new drugs. However, existing catalytic methods often face challenges when dealing with complex drug molecules, as these molecules are typically more complex than simple substrates. In particular, the formation of carbon-heteroatom (C–X) bonds is an ...

Synthesis of Molecular Borromean Links Featuring Trimeric Metallocages

The Borromean link is a topological structure composed of three independent yet interlocked rings, characterized by the fact that disconnecting any one ring results in the complete separation of the other two. This structure not only possesses aesthetic value but also holds significant research importance in molecular topology and supramolecular ch...

A Pickering-Emulsion-Droplet-Integrated Electrode for the Continuous-Flow Electrosynthesis of Oximes

Cyclohexanone oxime is a critical intermediate in the production of nylon-6, with global nylon-6 production projected to reach 8.9 million tons by 2024, leading to an increasing demand for cyclohexanone oxime. Traditional methods for synthesizing cyclohexanone oxime primarily involve the reaction of hydroxylamine (NH2OH) with cyclohexanone. However...

Capturing Aromatic Cr5 Pentagons in Large Main-Group Molecular Cages

Academic Background Transition metal clusters have long been a focus of chemical research due to their unique structures and electronic properties. Chromium (Cr), as one of the transition metals, is particularly notable for its interesting Cr-Cr bonding interactions and diverse structural arrangements. However, exploring the synthesis of polynuclea...

Synthesis and Reactivity of an Antimony(III) Dication

Synthesis and Reactivity of an Antimony(III) Dication

In enzyme catalysis, the proximity effect is a common phenomenon that forces reactions to occur by bringing two or more molecules close together. To achieve this effect, the active center requires multiple binding sites to preorganize reactants before the reaction. Although this effect has been extensively studied in enzyme catalysis, its applicati...